You prefer that biofuel manufacturers exploit the land rather than food growers?
Every acre used for growing biofuels is one less acre for growing food crops.
Actually, there are non-crop plants such as switchgrass, rapeseed, etc that can grow in places that are not normally used for food crops, especially in the desert, marshes, swamps, brine water, etc to be used for biofuels. So by that way, they won't compete against actual food crops. Also, it is possible that those third world countries can make money by cultivating those non-crop plants. As for invasive species....that's another story being researched right now.
The Third World countries have no reason to go into green technology since they are the one with abundant of resources..... especially oil. Its infrastructure is not well-developed yet to support green technology.
I mean.... Toyota Prius in Africa? comical.
Would it surprise you that South Africa is using one of the green technology extensively to produce synfuels/biofuels, especially since the early 1900s? The area had no oil but abundant in coal, but though the process of gasification and other methods to convert from coal to liquid fuel, they were able to achieve some sort of neutral carbon growth over its lifecycle.

