Not really. A friend of mine flew in Montreal from Ukraine, and two months later he got permanent resident in Canada.
That's because Québec has it's own, entirely separate evaluation, acceptance and residency application and approval process than the rest of Canada. Realistically applying to Québec for permanent resident status is almost as if one was applying to an entirely different country (than the process for approval for the rest of Canada.)
For residency visas (temp or permanent) Québec has a number of "special offers" for people who meet specific requirements (education, linguistic, financial, family already living in QUEBEC as Canadian citizens etc) provided the persons also agree to make Québec their permanent home (for a minimum number of years after becoming a permanent resident &/ citizen).
What most people outside of Canada (and even some in Canada) do not realize is that while Québec is officially a province within & part of Canada - in many very real and practical ways (legal, governmental, immigration/residency, linguistic etc) Québec is much more it's own country, or at least a country-within-a-country than it is a typical Canadian Province (vaguely like Washington DC is unique in the USA not only because it is the Country's capital, but also because it is NOT a part of any USA state ....It's a central PART of the USA, but is also separate in many fundamental and critical ways).
One simple "everyday" example is that most coupons, product warranties, and "Canada-wide campaigns" (merchandise, store, banking, auto sales etc) are NOT valid in the province of Québec and offers valid in Québec are typically ONLY valid in Québec.
Here's a brief explanation of the process for Canada and Québec
